Please use this identifier to cite or link to this item: http://repository.vnu.edu.vn/handle/VNU_123/29046
Title: Roles of nano-sized Au in the reduction of NOx by propene over Au/TiO2: An in situ DRIFTS study
Authors: Nguyen, Long Q.
Salim, Chris
Hinode, Hirofumi
Keywords: In situ DRIFTS;Nano-sized Au;Mechanism
Issue Date: 2010
Publisher: ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
Citation: ISIKNOWLEDGE
Abstract: A mechanistic study of the selective catalytic reduction (SCR) of NOx by C3H6 has been investigated over nano-sized Au/TiO2 catalyst using in situ diffuse reflectance Fourier transform infrared spectroscopy (DRIFTS). The formation and consumption of adsorbed species on the catalyst surface have been intensively studied during co-adsorption of reactants and reaction condition. The presence of nano-sized Au particles played an important role in the formation of oxygenated hydrocarbons, especially acetate species. Importantly, Au active sites were crucial to the formation of isocyanate intermediate compounds and contributed to the conversion of these intermediates to N2. The reaction mechanism of SCR over Au/TiO2 has been discussed on the basis of DRIFTS results.
Description: TNS06166 ; APPLIED CATALYSIS B-ENVIRONMENTAL Volume: 96 Issue: 3-4 Pages: 299-306
URI: http://repository.vnu.edu.vn/handle/VNU_123/29046
http://www.sciencedirect.com/science/article/pii/S0926337310000767
ISSN: 0926-3373
Appears in Collections:Bài báo của ĐHQGHN trong Web of Science

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