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Title: The Determing Activation Energy of Total Oxidation Reaction of m-xylene over La0,7Sr0,3BO3 (B = Mn, Fe, Ni) Perovskite Catalysts
Other Titles: Xác định năng lượng hoạt hóa của phản ứng oxy hóa hoàn toàn m-xylen trên các xúc tác perovskit La0,7Sr0,3BO3 (B = Mn, Fe, Ni)
Authors: Tran, Thi Thu Huyen
Tran, Thi Luyen
Nguyen, Thi Tuyet Mai
Keywords: perovskit;m-xylen
Issue Date: 2017
Publisher: ĐHQGHN
Series/Report no.: Tập 33;Số 4
Abstract: Perovskite-type oxides containing rare earth ions and transition metals are of interest for catalytic oxidation and reduction reactions associated with automotive exhaust emission control. They are known to exhibit a good catalytic activity in the total oxidation reaction of carbon monoxide or hydrocarbon and removal of nitrogen oxides. By partially substitution of A and B ions of the perovskite with others, a wide variety of mixed oxides A1-xA’xB1-yB’yO3 can be obtained, allowing the systematic modification of the catalytic properties. We presented the preparation and the catalytic properties of and La0.7Sr0.3BO3 (B = Mn, Fe, Ni) perovskites in total oxidation of m-xylene in previous report. Obtained results showed that they exhibit a good catalytic activity in total oxidation of m-xylene at relatively low reaction temperature. In present work, the activation energy of total oxidation reaction of m-xylene over these catalysts are determined. The results show that the activation energy of studied catalyst is ranging about from 11.5 to 13.4 kcal/mol. The replacement of Mn by Fe and Ni in La0.7Sr0.3MnO3 perovskite catalyst reduces the catalytic property of La0.7Sr0.3MnO3 catalyst and increases the activation energy of the total oxidation reaction of m-xylene.
Description: tr. 79-84
ISSN: 2588-1140.
Appears in Collections:Natural Sciences and Technology

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