Browsing by Subject CurieeWeiss behavior

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  • Magnetic-properties-of-some-transition-metal-Prussian-Blue-Analogs-with-composition-M3-M-C-N-6-2-xH2O_2016_Journal-of-Science-Advanced-Materials-and-D.pdf.jpg
  • Article


  • Authors: Heinz Nakotte; Manjita Shrestha; Sourav Adak; Michael Boergert; Vivien S. Zapf; Neil Harrison; Graham King; Luke L. Daemen (2016)

  • Magnetic data are reported for Prussian Blue Analogs (PBAs) of composition M3[M'(C,N)6]2·xH2O, where M = Mn, Co, Ni or Cu and M' = Cr, Fe or Co and x is the number of water molecules per unit cell. PBAs crystallize in cubic framework structures, which consist of alternating MIIIN6 and MIIC6 octahedra. Oc-cupancies of the octrahedra are not perfect: they may be empty and the charges are balanced by the oxygen atoms originating from guest water molecules at the lattice site (C or N site) or the interstitial site (between the octahedrals) of the unit cell. Large crystal-field splittings due to the octrahedral environment results in a combination of low- or high-spin configurations of lo...

Browsing by Subject CurieeWeiss behavior

Jump to: 0-9 A B C D E F G H I J K L M N O P Q R S T U V W X Y Z
or enter first few letters:  
Showing results 1 to 1 of 1
  • Magnetic-properties-of-some-transition-metal-Prussian-Blue-Analogs-with-composition-M3-M-C-N-6-2-xH2O_2016_Journal-of-Science-Advanced-Materials-and-D.pdf.jpg
  • Article


  • Authors: Heinz Nakotte; Manjita Shrestha; Sourav Adak; Michael Boergert; Vivien S. Zapf; Neil Harrison; Graham King; Luke L. Daemen (2016)

  • Magnetic data are reported for Prussian Blue Analogs (PBAs) of composition M3[M'(C,N)6]2·xH2O, where M = Mn, Co, Ni or Cu and M' = Cr, Fe or Co and x is the number of water molecules per unit cell. PBAs crystallize in cubic framework structures, which consist of alternating MIIIN6 and MIIC6 octahedra. Oc-cupancies of the octrahedra are not perfect: they may be empty and the charges are balanced by the oxygen atoms originating from guest water molecules at the lattice site (C or N site) or the interstitial site (between the octahedrals) of the unit cell. Large crystal-field splittings due to the octrahedral environment results in a combination of low- or high-spin configurations of lo...